Iron(II) oxide determination in rocks and minerals     

Sandra Andrade  Raphael HypolitoHorstpeter H.G.J. Ulbrich  Marinês L. Silva 《Chemical Geology》2002,182(1):85-89

The determination of FeO of geologic materials by modern instrumental methods (such as atomic absorption spectroscopy (AAS), inductively coupled plasma atomic emission spectroscopy (ICP-AES), X-ray fluorescence (XRF), etc.) cannot distinguish between different oxidation states of elements. In many cases, the oxidation state of Fe has to be known in order to perform several chemical calculations (norms, etc.) and discuss the reactions that occur during weathering, hydrothermal alteration and other processes. A modified Wilson method is proposed, giving reproducible results in a much shorter time than the classical method. Back-titration with potassium dichromate and an Fe(II) and ammonia sulphate solution is used, after dissolution of the sample powder in a heated HF/H₃PO₄ mixture and an ammonium vanadate solution. This modified method, tested with several international reference materials, gives reliable results, equivalent to the ones cited in the literature for the reference materials.  相似文献   

Experimental Study on Mine Spoils During Superficial Geochemistry Processes     

王一先  白正华 《中国地球化学学报》2002,21(4)

Based on the mineral and chemical compositions of spoils taken from the Shilu Cu-Mo deposit and Hetai gold deposit, the leaching and batch experiments were made on spoils taken from these two deposits using the leaching column designed by the authors. The experimental results showed that it is not always true that the mine drainage is acidic. Its acidity depends on acid-buffering capacity of gangue, host rock and its alteration mineral assemblage. The composition of the drainage water is related with the interaction between superficial or underground water and solid materials in the spoils, including minerals, hydroxides and amorphous substances. The leaching extent of the element is related with its occurrence form in the deposit. The preferential flow results in leaching-out of heavy metals in large amounts. So it is important to prevent the generating of preferential flow in the system. The results will provide very important grounds for the comprehensive management of land and ecological rehabilitation of the mine site.  相似文献   

Determining Q of near-surface materials from Rayleigh waves     

Jianghai Xia  Richard D. Miller  Choon B. Park  Gang Tian 《Journal of Applied Geophysics》2002,51(2-4)

High-frequency (≥2 Hz) Rayleigh wave phase velocities can be inverted to shear (S)-wave velocities for a layered earth model up to 30 m below the ground surface in many settings. Given S-wave velocity (V_S), compressional (P)-wave velocity (V_P), and Rayleigh wave phase velocities, it is feasible to solve for P-wave quality factor Q_P and S-wave quality factor Q_S in a layered earth model by inverting Rayleigh wave attenuation coefficients. Model results demonstrate the plausibility of inverting Q_S from Rayleigh wave attenuation coefficients. Contributions to the Rayleigh wave attenuation coefficients from Q_P cannot be ignored when Vs/V_P reaches 0.45, which is not uncommon in near-surface settings. It is possible to invert Q_P from Rayleigh wave attenuation coefficients in some geological setting, a concept that differs from the common perception that Rayleigh wave attenuation coefficients are always far less sensitive to Q_P than to Q_S. Sixty-channel surface wave data were acquired in an Arizona desert. For a 10-layer model with a thickness of over 20 m, the data were first inverted to obtain S-wave velocities by the multichannel analysis of surface waves (MASW) method and then quality factors were determined by inverting attenuation coefficients.  相似文献   

华北地台北缘地球物理场特征与金属矿床预测   总被引：5，自引：0，他引：5       下载免费PDF全文

江为为  管志宁  郝天珧  黄临平 《地球物理学报》2002,45(2):233-245

对华北地台北缘的地球物理场特征进行了探讨,根据重、磁异常数据反演计算了该地区的莫霍界面、居里界面、磁性界面的起伏.利用地球物理场资料和反演计算结果对该地区的构造格架和断裂进行了推断,同时预测了9个成矿远景区:(1)集宁一呼和浩特金成矿区;(2)张家口一赤城金、银多金属成矿区;(3)密云一高岭金、铜成矿区;(4)青龙一马兰庄金成矿区;(5)秦皇岛、金多金属成矿区;(6)郝家营多金属成矿区;(7)承德地区金、多金属成矿区;(8)赤峰一喀喇沁旗金成矿区;(9)宁城东金、多金属成矿区.  相似文献   

红板岩材料隐式本构模型的建立及其应用研究     

邹光华  朱建明 《工程地质学报》2003,11(3):258-262

针对红板岩材料在岩土工程中所表现的大量模糊的和不确定的因素等特点,基于人工神经网络的学习能力,借助于室内岩石力学试验,进行了对该材料的力学本构特性进行了神经网络模拟研究,提出了隐式本构模型的思想和方法,并通过该方法对该岩石的流变试验结果进行学习,获得了以网络权值结构保存的力学特性知识,由此得到了表征红板岩应力应变本构关系的隐式本构模型。应用结果表明,该方法对岩土类材料本构关系的模拟研究具有很好的应用前景。  相似文献   

细菌浸铜技术在紫金山铜矿的应用   总被引：4，自引：0，他引：4  

胡世丽  王观石 《江苏地质》2003,27(1):31-33

介绍了生物浸矿技术在紫金山铜矿的应用及在这一过程中发现的一些问题，并提出了有待进一步解决的一些问题。  相似文献   

充电激发极化法在金属矿上的应用   总被引：1，自引：0，他引：1  

杨立功 《矿产与地质》2003,17(1):34-36,26

充电激发极化法是矿山物探的一种主要方法，其兼有充电法与激发极化法的特点，可利用已有的工程，最大限度地了解地下三度空间地球物理场的分布情况，解决地质问题。概述了其理论基础和方法技术，并列举了该方法在多个金属矿上的应用实例。  相似文献   

铅锌矿山开发导致的重金属在环境介质中的积累   总被引：35，自引：4，他引：35  

杨元根  刘丛强  张国平  吴攀  朱维晃 《矿物岩石地球化学通报》2003,22(4):305-309

以连续提取法和相关性分析研究了土法冶炼锌、铅锌和矿山开采导致的重金属在废渣及环境介质土壤、溪流沉积物中的积累，并分析了其环境危害性。结果显示，贵州赫章土法炼锌导致的重金属Pb、Zn、Cd在环境介质中的积累相当高。水城杉树林铅锌矿山开采引起的重金属积累则相对较低，但也明显高于背景值；土壤和沉积物中的铁矿物对重金属有强烈的固定作用。除残渣态外，Pb、Zn在土壤、炼锌废渣中主要呈铁锰氧化物结合态，沉积物中则为碳酸盐结合态。可交换态Pb、Zn含量变异较大，但在炼锌废渣、土壤中含量明显高于河流沉积物，暗示铅锌矿开发对土壤环境的潜在危害更大。  相似文献   

内蒙古矿山地质环境问题及防治对策   总被引：4，自引：0，他引：4  

王剑民 《西北地质》2003,36(3):97-101

矿产资源在国民经济建设中起着十分重要的作用。但长期以来，由于在矿产资源开发利用中忽视矿山环境保护，使本已十分脆弱的矿山生态环境问题雪上加霜，严重影响和制约了经济社会的持续、健康发展。内蒙古自治区是矿产资源大省，由矿产资源开发引发的次生地质环境同题非常突出．土地沙化、地面塌陷、滑坡、泥石流、水质污染、地下水位下降及煤层自燃等，使植被面积减少、生态和水环境破坏、空气污染，人类生存环境不断恶化。随着人口的增长和经济发展对矿产资源需求的不断增大，加大矿山地质环境保护立法，研究和制定矿山地质环境防治措施与对策，减少地质灾害，实现矿产资源既能满足当代人需求，又能造富子孙后代的可持续发展目标。  相似文献   

甘肃北山公婆泉盆地中生代地层特征与砂岩型铀成矿条件分析     

刘帅  管太阳  巫建华 《华东地质学院学报》2003,26(1):41-47

根据野外实地考察，综合前人的工作资料，从地层结构、层位、沉积体系、岩性及形成砂岩型铀矿的条件出发，概括了公婆泉盆地中生代地层的主要特征；确定了目的层并浅要分析了砂岩型铀成矿条件，对下一步铀矿找矿工作具有一定的现实意义。  相似文献